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year 10, Issue 2 (2024)
JRA 2024, 10(2): 163-186 |
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Fadaei H, Emami S M, Karimi Jashni A, Ismailzadeh A. (2024). Identification and Measurement of Air Pollutants in the Historical Site of Naqsh-e Rostam, Fars, Iran. JRA. 10(2), 163-186. doi:10.61882/jra.10.2.421
URL: http://jra-tabriziau.ir/article-1-421-en.html
URL: http://jra-tabriziau.ir/article-1-421-en.html
1- Research Centre for Conservation and Restoration of Cultural Relics, Research Institute of Cultural Heritage and Tourism, Tehran, Iran , hfadaii@yahoo.com
2- Faculty of Conservation and Restoration, Art University of Isfahan, Isfahan, Iran
3- Faculty of Materials Science and Civil Engineering, Shiraz University, Shiraz, Iran
4- Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran
2- Faculty of Conservation and Restoration, Art University of Isfahan, Isfahan, Iran
3- Faculty of Materials Science and Civil Engineering, Shiraz University, Shiraz, Iran
4- Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran
Abstract: (2338 Views)
Naqsh-e Rostam is the name of a stone heritage site with memories from the Elamite, Achaemenid and Sasanian periods, which is located in the south of Iran, in the north of Marvdasht city, five kilometers from the Persepolis world heritage site. Proximity of polluting sources to this site, especially: Shiraz Petrochemical company (located in the city of Marvdasht and 17 km southwest of Naqsh-e Rostam), busy roads, extensive agriculture in the region and the use of a large amount of chemical fertilizers and herbicides, as well as the burning of plant residues on agricultural lands after harvesting crops, has caused many concerns for the possible erosion of the stone reliefs of the site. Therefore, one of the most important goals of this research is to identify and measure the amount of mentioned pollutants in Naqsh-e Rostam site with laboratory studies. Smpling of the air in the region and headspace solid phase micro extraction (HS-SPME) were done using synthetic fibers and gas samplers. Also, gas chromatograph connected to mass spectrometer and ion chromatograph were used for analysis. The results show that the diversity and concentration of pollutant species in Naqsh-e Rostam is very high and the most important source is related to the petrochemical company. The historical and natural capacities of Naqsh-e Rostam site and other historical sites of the region require that in the long term, the pattern of sustainable development of the region should be changed from industries with high volume of environmental pollutants to tourism.
Keywords: Air pollutants, Naqsh-e Rostam historical site, Erosion, Shiraz petrochemical company, Gas Chromatography - Mass Spectrometry (GC-MS), Ion Chromatography (IC), Marvdasht
Technical Note: Original Research |
Subject:
Archaeometry
Received: 2024/06/29 | Accepted: 2024/12/29
Received: 2024/06/29 | Accepted: 2024/12/29
References
1. Air Pollution Research Unit (1998). Investigation of air pollution in Shiraz Petrochemical Complex. Tehran: Oil Industry Research Institute. Unpublished report. [in Persian].
2. Ansari Lari, A., & Ansari, M. (2016). Estimate the amount of soil erosion in Marvdasht plain (Iran, Fars) by RUSLE Mode, Quantitative Geomorphological Research, 4(4), 134-149. [in Persian].https://dor.isc.ac/dor/20.1001.1.22519424.1395.4.4.9.2
3. Armarego, W. L. F. (2017). Chapter 3 - Purification of Organic Chemicals, (Purification of Laboratory Chemicals, Eighth Edition): Butterworth-Heinemann, 95. [DOI:10.1016/B978-0-12-805457-4.50003-3]
4. Baig, N., Sajid, M. (2017). Applications of layered double hydroxides based electrochemical sensors for determination of environmental pollutants: A review. Trends in Environmental Analytical Chemistry, 16, 1. doi:
https://doi.org/10.1016/j.teac.2017.10.003 [DOI:10.1016/j.teac.2017.10.003.]
5. Buurma, N. J. (2017). Aggregation and reactivity in aqueous solutions of cationic surfactants and aromatic anions across concentration scales. Current Opinion in Colloid & Interface Science, 32, 69. doi:
https://doi.org/10.1016/j.cocis.2017.10.005 [DOI:10.1016/j.cocis.2017.10.005.]
6. Carvalho, S., Delgado, R., Félix, V. (2010). Evaluation of the binding ability of a macrobicyclic receptor for anions by potentiometry and molecular dynamics simulations in solution. Tetrahedron, 66(45), 8714. doi:
https://doi.org/10.1016/j.tet.2010.09.006 [DOI:10.1016/j.tet.2010.09.006.]
7. Crowley, P. J. (1984). 1.07 - Use as Agrochemicals A2 - Katritzky, Alan R, (In C. W. Rees (Ed.). Comprehensive Heterocyclic Chemistry, Oxford: Pergamon, 185. [DOI:10.1016/B978-008096519-2.00007-2]
8. Girotti, S., Ferri, E. N., Fumo, M. G., Maiolini, E. (2008). Monitoring of environmental pollutants by bioluminescent bacteria. Analytica Chimica Acta, 608(1), 2. doi:
https://doi.org/10.1016/j.aca.2007.12.008 [DOI:10.1016/j.aca.2007.12.008.]
9. Gupta, P. K. (2018). Chapter 5 - Pesticides (agrochemicals). Illustrated Toxicology: Academic Press, 165. [DOI:10.1016/B978-0-12-813213-5.00005-5]
10. Haddad, K. (2004). A study of air pollution in Marvdasht city. Fars: General Department of Environment of Fars, Unpublished report. [in Persian].
11. Jarque, S., Bittner, M., Blaha, L., Hilscherova, K. (2016). Yeast Biosensors for Detection of Environmental Pollutants: Current State and Limitations. Trends in Biotechnology, 34(5), 408. doi:
https://doi.org/10.1016/j.tibtech.2016.01.007 [DOI:10.1016/j.tibtech.2016.01.007.]
12. Karami, H., Farmer, H., Alahyari, A., & Taghizadeh, M. M. (2018). Investigating air pollutants caused by burning wheat straw and stubble, case study: Marvdasht city, Fars province. Paper presented at the Second National Conference on Civil Engineering and Sustainable Development. Islamic Azad University, Estahban branch, Estehban, 10 Mar 2018. [in Persian].
13. Karanam, P., Reddy, G. M., Koppolu, S. R., Lin, W. (2018). Recent topics of phosphine-mediated reactions. Tetrahedron Letters, 59(2), 59. doi:
https://doi.org/10.1016/j.tetlet.2017.11.051 [DOI:10.1016/j.tetlet.2017.11.051.]
14. Kohlmeier, M. (2015). Chapter 5 - Fatty Acids. Nutrient Metabolism, Second Edition, San Diego: Academic Press, 111. [DOI:10.1016/B978-0-12-387784-0.00005-5]
15. Lamichhane, S., Bal Krishna, K. C., Sarukkalige, R. (2016). Polycyclic aromatic hydrocarbons (PAHs) removal by sorption: A review. Chemosphere, 148, 336. doi:
https://doi.org/10.1016/j.chemosphere.2016.01.036 [DOI:10.1016/j.chemosphere.2016.01.036.]
16. List, G. R., Kenar, J. A., Moser, B. R. (2017). Chapter 1 - History of Fatty Acids Chemistry A2 - Ahmad, Moghis U. Fatty Acids: AOCS Press, 1.
17. Lowther, H. (1964). 15 - Aromatic Halogen Compounds. Organic Chemistry: Pergamon, 136. [DOI:10.1016/B978-1-4831-9673-2.50020-9]
18. O'Donoghue, J. L. (2007). 69 - Organic Chemicals A2 - Gilman, Sid. Neurobiology of Disease, Burlington: Academic Press, 745. [DOI:10.1016/B978-012088592-3/50071-2]
19. Ouyang, G. (2012). 8 - SPME and Environmental Analysis A2 - Pawliszyn, Janusz. Handbook of Solid Phase Microextraction, Oxford: Elsevier, 251. [DOI:10.1016/B978-0-12-416017-0.00008-5]
20. Pawliszyn, J., Vuckovic, D., Mirnaghi, F.,Risticevic, S. (2012). 5 - Automated SPME Systems. Handbook of Solid Phase Microextraction, Oxford: Elsevier, 135. [DOI:10.1016/B978-0-12-416017-0.00005-X]
21. Pichon, V., Chapuis-Hugon, F. (2008). Role of molecularly imprinted polymers for selective determination of environmental pollutants-A review. Analytica Chimica Acta, 622(1), 48. doi:
https://doi.org/10.1016/j.aca.2008.05.057 [DOI:10.1016/j.aca.2008.05.057.]
22. Raisi Ardakani, E. (2010). Investigating the hydrogeological zone in Persepolis world heritage site. Department of Earth Sciences, Shiraz University. unpublished report. Document center of Persepolis base. [in Persian].
23. Shirey, R. E. (2012). 4 - SPME Commercial Devices and Fibre Coatings A2 - Pawliszyn, Janusz. Handbook of Solid Phase Microextraction, Oxford: Elsevier, 99. [DOI:10.1016/B978-0-12-416017-0.00004-8]
24. Smith, P. W. G., Tatchell, A. R. (1969). Chapter III - Aromatic Halogen Compounds. Aromatic Chemistry: Pergamon, 46. [DOI:10.1016/B978-0-08-012948-8.50006-1]
25. Song, L., Xu, Z., Kang, J., Cheng, J. (1997). Analysis of environmental pollutants by capillary electrophoresis with emphasis on micellar electrokinetic chromatography. Journal of Chromatography A, 780(1), 297. doi:
https://doi.org/10.1016/S0021-9673(97)00365-8 [DOI:10.1016/S0021-9673(97)00365-8.]
26. Starek-Świechowicz, B., Budziszewska, B., Starek, A. (2017). Hexachlorobenzene as a persistent organic pollutant: Toxicity and molecular mechanism of action. Pharmacological Reports, 69(6), 1232. doi:
https://doi.org/10.1016/j.pharep.2017.06.013 [DOI:10.1016/j.pharep.2017.06.013.]
27. Vahidzadeh, Reza (2009). Air pollution in Haftepe and Chaghazanbil: the role of environmental analysis in the preventive protection of historical materials in these areas. Proceedings of 7th Conference on Conservation and Restoration of Cultural Relics and Architectural Decorations, 2004. By effort: Rasul Vatan Dost. Tehran: Research Institute of Cultural Heritage and Tourism, 9-25. [in Persian].https://rcccr.richt.ir/documents/58915/329905/8th-maremmat.pdf/b9fa62ff-8e2b-ae0c-d7f0-411f85a40807?t=1717843084712
28. Vanden Berghe, L., Schippmann, k. (1985). Les Reliefs Rupestres d'Elymaide (Iran) de l'Epoque Parthe. Iranica Antiqua. French Edition. ISBN 13: 9789068310689. 175 pages.
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