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:: Volume 2, Number 2 (2017) ::
JRA 2017, 2(2): 49-61 Back to browse issues page
Dating Feasibility of Unknown Historic Scripts through Thermal, Spectroscopic and Microscopic Identification of Paper Materials
Zohreh Ghayeni1, Siyamak Safapour *2
1- M.A. Tabriz Islamic Art University
2- Assistant Professor Tabriz Islamic Art University , s.safapour@gmail.com
Abstract:   (390 Views)

Historic papers contain valuable information about national, cultural, artistic and historical identity and values of every civilization. Identification of paper materials such as fiber type, sizing, and other materials can significantly help to obtain valuable information concerning old civilizations, their attitude, culture, geographical origin, and etc. However, there are some manuscripts that their writing date remains still unknown. Qualitative and quantitative analytical methods can be used as a tool to identify paper materials and therefore dating of historic papers as a cultural piece. In this research work, the dating feasibility of four unknown historic paper scripts was investigated through analysis and comparison of their materials like characteristic and type of fiber and sizing material with four known samples belonging to Safavid period. For this purpose, different techniques such as optical microscopy, color indictor assay, Fourier Transform Infrared spectroscopy (FTIR), Thermal Gravimetric Analysis (TGA), and Differential Scanning Calorimetry (DSC) were used to characterize paper materials. Using each characterization method, some information about physical, chemical, apparent form, and genus of paper materials were obtained. The results of fiber identification tests including optical microscopy and color indicators assay revealed that, except one sample made of kenaf fiber, all samples were made of flax fibers and no wooden fiber was used in paper making. FTIR data confirmed the presence of cellulose and hemi-cellulose and lack of lignin within all paper samples. Moreover, sizing material used for paper making was polysaccharide type, i.e., starch. TGA and DSC analyses results showed that depending on its thermal and chemical history, each sample had peculiar thermal behavior. Furthermore, compared to cellulose, hemi-cellulose possessed lower thermal stability. Overall, the results of this study revealed that dating of unknown samples through combination of thermal analysis and other characterization methods is possible, so the unknown samples belong to Safavid period. It is to be mentioned that the main goal of this research was dating unknown samples made of papers materials, which in this case all of them were similar. Although some samples may belong to different period, other parameters such as type of contents, differences in aesthetics, type of script, and etc. may be used to distinguish the sampled belonging to the same period. The data obtained in this research can be used in preparation of database for possible identification and dating of unknown historic samples.

Keywords: Historic Paper, Dating, Fourier Transform Infra-Red Spectroscopy, Thermal Analysis
Full-Text [PDF 946 kb]   (128 Downloads)    
Technical Note: Original Research | Subject: Archaeometry
Received: 2016/09/26 | Accepted: 2017/01/23 | Published: 2017/03/17 | ePublished: 2017/03/17
Turkish Abstract [HTM 51 KB]  (7 Download)
References
1. Agrawal, O. P., & Barkeshli, M. (1997). Conservation of books, manuscripts and paper documents. INTACH.
2. Azimi, H. (2012). Paper in Iranian-Islamic scripts. Faslname-yi motaleaat- e Melli Ketabdari va Sazmandehi-yi Etelaat, 146-1308. [in Persian]
3. Bayer, G., & Wiedemann, H. G. (1983). Thermoanalytical measurements in archaeometry. Thermochimica Acta, 69(1-2), 167-173.
4. Budrugeac, P., Miu, L., Bocu, V., Wortman, F., & Popescu, C. (2003). Thermal degradation of collagen-based materials that are supports of cultural and historical objects. Journal of thermal analysis and calorimetry, 72(3), 1057-1064.
5. Cabrales, L., & Abidi, N. (2010). On the thermal degradation of cellulose in cotton fibers. Journal of thermal analysis and calorimetry, 102(2), 485-491.
6. Cardwell, R. D. Luner, P. (1976a). Thermogravimetric analysis of pulps Part I: Kinetic treatment of isothermal pyrolysis of cellulose. Wood Sceience and Technology 10(2): 131-147.
7. Cardwell, R. D. Luner, P. (1976b). Thermogravimetric analysis of pulps part II: Kinetics for dynamic thermogravimetric analysis. Wood Science and Technology 10(3): 183-198.
8. Cardwell, R. D. Luner, P. (1978a). Thermogravimetric analysis of pulps III: TGA Profiles. Preservation of Paper and Textiles of Historic and Artistic Value, Chapter 24: 362–381.
9. Cardwell, R. D. Luner, P. (1978b). Thermogravimetric analysis of pulps IV: Thermal Stability Indices. Preservation of Paper and Textiles of Historic and Artistic Value, Chapter 25: 382–396.
10. Ceylan, Ö., Van Landuyt, L., Rahier, H., & De Clerck, K. (2013). The effect of water immersion on the thermal degradation of cotton fibers. Cellulose, 20(4), 1603-1612.
11. Derrick, M. R., Stulik, D., & Landry, J. M. (2000). Infrared spectroscopy in conservation science. Getty Publications.
12. Duswalt, A. A. (1977). Thermal analysis study of paper permanence. Preservation of paper and textiles of historic and artistic value, 352-361.
13. Franceschi, E., Luciano, G., Carosi, F., Cornara, L., & Montanari, C. (2004). Thermal and microscope analysis as a tool in the characterisation of ancient papyri. Thermochimica acta, 418(1), 39-45.
14. Gorassini, A., Calvini, P., & Baldin, A. (2008, June). Fourier transform infrared spectroscopy (FTIR) analysis of historic paper documents as a preliminary step for chemometrical analysis. In Italy: CMA4CH 2nd Mediterraneum meeting on multivariate analysis and chemometry for cultural heritage and environment (Vol. 2, pp. 47-48).
15. Gregorova, A. (2013). Application of differential scanning calorimetry to the characterization of biopolymers. INTECH Open Access Publisher.
16. Feller, R. L., Lee, S. B., & Bogaard, J. (1986). The kinetics of cellulose deterioration. In Historic textile and paper materials: conservation and characterization (pp. 329-347). American Chemical Society.
17. Ilvessalo-Pfäffli, M. S. (1995). Fiber atlas: identification of papermaking fibers. Springer Science & Business Media.
18. Karimi, A. H., and Vatankhah, G. R. (2011). Identification of Iranian painting binders using wet chemistry, Journal of Restoration and Research, 4(7): 92-100. [in Persian]
19. Kasiri, M. B., Yoonesi, B., Yajam, A. (2016) Identify historical paper fibers to Dating feasibility of unknown samples, Journal of Research on Archaeometry.2(1):29-38. [in Persian]
20. Marcolli, C., & Wiedemann, H. (2001). Distinction of original and forged lithographs by means of thermogravimetry and Raman spectroscopy. Journal of thermal analysis and calorimetry, 64(3), 987-1000.
21. Nasir-Ahmadi, A., and Halek, F.S. (2011). Infrared Spectroscopy. Karaj: Islamic Azad University.
22. Pandey, K. K. (1999). A study of chemical structure of soft and hardwood and wood polymers by FTIR spectroscopy. Journal of Applied Polymer Science, 71(12), 1969-1975.
23. Pires, J., & Cruz, A. J. (2007). Techniques of thermal analysis applied to the study of cultural heritage. Journal of Thermal Analysis and Calorimetry, 87(2), 411-415.
24. Shapour-Aabadi, F. B., and Bahadori, R. (2003). Determination of antiquity of documents and scripts uing experimental and laboratory methods. Nameh-yi baharestan. 3rd year. Shomare-i Daftar, 526: 6-526. [in Persian]
25. Smoke, G. (2004). Pulp and Paper Technology. (A. Mir-Shakraie, Trans.). Tehran: Aeizh. [in Persian] (Original work published 1934).
26. Špérová, M., Nasadil, P., Průšová, A., & Kučerík, J. (2012). A hint on the correlation between cellulose fibers polymerization degree and their thermal and thermo-oxidative degradation. Journal of thermal analysis and calorimetry, 110(1), 71-76.
27. Trafela, T., Strlicˇ, M., Kolar, J., Lichtblau, D. A., Anders, M., Mencigar, D. P., & Pihlar, B. (2007). Nondestructive analysis and dating of historical paper based on IR spectroscopy and chemometric data evaluation. Analytical chemistry, 79(16), 6319-6323.
28. Wiedemann, H. G., & Bayer, G. (1992). Approach to ancient Chinese artifacts by means of thermal analysis. Thermochimica acta, 200(1-2), 215-255.
29. Wiedemann, H. G., & Boller, A. (1996). Thermal analysis of Codex Huamantla and other Mexican papers. Journal of Thermal Analysis and Calorimetry, 46(3-4), 1033-1045.
30. Wiedemann, H. G., Günter, J. R., & Oswald, H. R. (1996). Investigation of ancient and new Japanese papers. Thermochimica acta, 282, 453-459.
31. Yang, H., Yan, R., Chen, H., Lee, D. H., & Zheng, C. (2007). Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel, 86(12), 1781-1788.
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Ghayeni Z, Safapour S. Dating Feasibility of Unknown Historic Scripts through Thermal, Spectroscopic and Microscopic Identification of Paper Materials. JRA. 2017; 2 (2) :49-61
URL: http://jra-tabriziau.ir/article-1-66-en.html
Volume 2, Number 2 (2017) Back to browse issues page
پژوهه باستان سنجی Journal of Research on Archaeometry
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