Study of Effects of Tiophanate Methyl and Carbendazim Fungicides on Paper Structure by Application of Fourier Transform Infrared Spectroscopy - Journal of Research on Archaeometry
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year 2, Issue 1 (2016)                   JRA 2016, 2(1): 55-66 | Back to browse issues page

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Abdolalizadeh M, Azadi Boyaghchi M, Mohammadi Achachlouei M, Bahremandi Poorfard R. (2016). Study of Effects of Tiophanate Methyl and Carbendazim Fungicides on Paper Structure by Application of Fourier Transform Infrared Spectroscopy. JRA. 2(1), 55-66. doi:10.29252/jra.2.1.55
URL: http://jra-tabriziau.ir/article-1-57-en.html
Study of Effects of Tiophanate Methyl and Carbendazim Fungicides on Paper Structure by Application of Fourier Transform Infrared Spectroscopy
Mahboob Abdolalizadeh * 1, Mehrnaz Azadi Boyaghchi2 , Mohsen Mohammadi Achachlouei2 , Rana Bahremandi Poorfard3
1- Art University of Isfahan , mahboob9067@yahoo.com
2- Art University of Isfahan
3- Tabriz Islamic Art University
Abstract:   (6459 Views)

Most of fungicides for prevention of biological degradation in historic papers, firstly have been used in the other scientific and industrial fields such as material preservation, agriculture and medical science. Other scientific fields have a great importance in the conservation of historic relics especially paper relics. Therefore, Tiophanate methyl and Carbendazim fungicides were studied for application in the conservation and restoration of paper relics. Each of these materials is one of most important and applied materials in agriculture which are effective against wide range of biological factors. Conservation material should not have intensive structural effects on paper relics. Accordingly, it is required to evaluate effects of Tiophanate methyl and Carbendazim treatments on paper. Fourier Transform Infrared Spectroscopy (FTIR) is one of most important methods for structural changes of paper. For the study, laboratory samples were prepared from filter paper. Samples were treated with Tiophanate methyl (dissolved in methanol) and Carbendazim (dissolved in distilled water) in 100ppm and 200ppm concentrations by spray method. Blank and treated samples were aged according to ISIRI4706 standard method for 288 hours. After aging, structural changes have been studied by application of Fourier Transform Infrared Spectroscopy. Results showed that spectra of treated paper samples with Tiophanate methyl and Carbendazim have no structural deformation in both 100ppm and 200ppm concentrations. According to resulted spectra, it was clear that treatment materials have been added to paper but there was not any sign of paper degradation. Accelerated aging caused to production of carbonyl adsorption of the spectra in 1742 cm-1. It was indicated decay of cellulose and presence of new degradation products which results to aesthetical change of paper. Aged samples compared with unaged ones did not show structural deformation in paper due to treatment materials and there was not any sign of breakdown in cellulose linkages. The both of 100ppm and 200ppm treated samples were without damage after accelerated aging. In general, the both treatments do not affect paper structure according to results of infrared spectra.

Keywords: Fungicide, Thiophanate-methyl, Carbendazim, Paper, FTIR, Conservation, Restoration
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Technical Note: Original Research | Subject: Conservation Science
Received: 2016/05/12 | Accepted: 2016/08/23 | Published: 2016/09/22 | ePublished: 2016/09/22
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References
1. Aboul-Enein, Y., Bunaciu, A. A., Udriştioiu, F. M., & Tanase, I. G. (2012). Application of micro-Raman and FT-IR spectroscopy in forensic analysis of questioned documents. Gazi University Journal of Science, 25(2), 371-375.
2. Adelantado, C., Bello, C., Borrell, A., & Calvo, M. A. (2005). Evaluation of the antifungal activity of products used for disinfecting documents on paper in archives. Restaurator, 26(4), 235-238. [DOI:10.1515/REST.2005.235]
3. Bacilkova, B. (2006). Study on the Effect of Butanol Vapours and other Alcohols on Fungi. Restaurator, 27(3), 186-199. [DOI:10.1515/REST.2006.186]
4. Bollen, G. J. (1972). A comparison of the in vitro antifungal spectra of thiophanates and benomyl. Netherlands Journal of Plant Pathology, 78(2), 55-64. [DOI:10.1007/BF02077557]
5. Ciolacu, D., Kovac, J., & Kokol, V. (2010). The effect of the cellulose-binding domain from Clostridium cellulovorans on the supramolecular structure of cellulose fibers. Carbohydrate research, 345(5), 621-630. [DOI:10.1016/j.carres.2009.12.023]
6. Courtney, G. F. (1977). Stability of thiophanate-methyl in aqueous dispersion. Pesticide Science, 8(3), 211-213 [DOI:10.1002/ps.2780080305]
7. Cycon, M., Wojcik, M., & Piotrowska-Seget, Z. (2011). Biodegradation kinetics of the benzimidazole fungicide thiophanate-methyl by bacteria isolated from loamy sand soil. Biodegradation, 22(3), 573-583. [DOI:10.1007/s10532-010-9430-4]
8. Fabbri, A. A., Ricelli, A., Brasini, S., & Fanelli, C. (1997). Effect of different antifungals on the control of paper biodeterioration caused by fungi. International biodeterioration & biodegradation, 39(1), 61-65. [DOI:10.1016/S0964-8305(97)00001-2]
9. Farag, A., Ebrahim, H., ElMazoudy, R., & Kadous, E. (2011). Developmental toxicity of fungicide carbendazim in female mice. Birth Defects Research Part B: Developmental and Reproductive Toxicology, 92(2), 122-130. [DOI:10.1002/bdrb.20290]
10. Garg, K. L. (1995). Use of homoeopathic drugs as antifungal agent for the protection of books and paper materials. In Biodeterioration of cultural property 3: proceedings of the 3rd international conference on biodeterioration of cultural property, July 4-7, 1995, Bangkok, Thailand (pp. 104-115). Office of Archaeology and National Museums. Conservation Science Division.
11. Gisi, U., Kuck, K. H., Russell, P. E., & Lyr, H. (2005). Modern fungicides and antifungal compounds IV. Alton, Hampshire: BCPC.
12. Gorassini, A., Calvini, P., & Baldin, A. (2008, June). Fourier Transform Infrared spectroscopy (FTIR) analysis of historic paper documents as a preliminary step for chemometrical analysis. In Atti del Congresso: Multivariate Analysis and Chemometry Applied to Environment and Cultural Heritage, second ed., Ventotene, Italy (pp. 1-4).
13. Gutarowska, B., Skora, J., Zduniak, K., & Rembisz, D. (2012). Analysis of the sensitivity of microorganisms contaminating museums and archives to silver nanoparticles. International Biodeterioration & Biodegradation, 68, 7-17. [DOI:10.1016/j.ibiod.2011.12.002]
14. Hajji, L., Boukir, A., Assouik, J., Lakhiari, H., Kerbal, A., Doumenq, P., ... & De Carvalho, M. L. (2015). Conservation of Moroccan manuscript papers aged 150, 200 and 800years. Analysis by infrared spectroscopy (ATR-FTIR), X-ray diffraction (XRD), and scanning electron microscopy energy dispersive spectrometry (SEM–EDS). Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 136, 1038-1046. [DOI:10.1016/j.saa.2014.09.127]
15. Hirschfeld, T., Ellner, F., Buschhaus, H., Goßmann, M., & Büttner, C. (2010). Investigations in the mode of action of thiophanate-methyl in Fusarium spp. Vom Lebensmittel zum Genussmittel–was essen wir morgen, 262-264.
16. Ibrahim, M., Osman, O., & Mahmoud, A. A. (2011). Spectroscopic analyses of cellulose and chitosan: FTIR and modeling approach. Journal of Computational and Theoretical Nanoscience, 8(1), 117-123. [DOI:10.1166/jctn.2011.1668]
17. Lamberth, C., & Dinges, J. (Eds). (2012). Bioactive Heterocyclic Compound Classes: Pharmaceuticals. John Wiley & Sons. [DOI:10.1002/9783527664412]
18. Michaelsen, A., Pinzari, F., Barbabietola, N., & Pi-ar, G. (2012). Monitoring the effects of different conservation treatments on paper-infecting fungi. International Biodeterioration & Biodegradation
19. Nauha, E., Saxell, H., Nissinen, M., Kolehmainen, E., Schafer, A., & Schlecker, R. (2009). Polymorphism and versatile solvate formation of thiophanate-methyl. CrystEngComm, 11(11), 2536-2547. [DOI:10.1039/b905511h]
20. Pesticide residues in food: (2006). toxicological evaluations, sponsored jointly by FAO and WHO, with thesupport of the International Programme on Chemical Safety / Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and WHO Core Assessment Group, Rome, Italy, 3–12 October 2006.
21. Rakotonirainy, M. S., Fohrer, F., & Flieder, F. (1999). Research on fungicides for aerial disinfection by thermal fogging in libraries and archives. International biodeterioration & biodegradation, 44(2), 133-139. [DOI:10.1016/S0964-8305(99)00075-X]
22. Sanches, N. B., Pedro, R., Diniz, M. F., da Costa Mattos, E., Cassu, S. N., & Dutra, R. D. C. L. (2013). Infrared spectroscopy applied to materials used as thermal insulation and coatings. Journal of Aerospace Technology and Management, 5(4), 421-430. [DOI:10.5028/jatm.v5i4.265]
23. Sandahl, M., Mathiasson, L., & Jönsson, J. Å. (2000). Determination of thiophanate-methyl and its metabolites at trace level in spiked natural water using the supported liquid membrane extraction and the microporous membrane liquid–liquid extraction techniques combined on-line with high-performance liquid chromatography. Journal of Chromatography A, 893(1), 123-131. [DOI:10.1016/S0021-9673(00)00697-X]
24. Sequeira, S., Cabrita, E. J., & Macedo, M. F. (2012). Antifungals on paper conservation: An overview. International Biodeterioration & Biodegradation, 74, 67-86. [DOI:10.1016/j.ibiod.2012.07.011]
25. Van der Kerk, G. J. M. (1973). Chemical and biochemical aspects of systemic fungicides. EPPO Bulletin, 2(10), 5-21. [DOI:10.1111/j.1365-2338.1973.tb02092.x]
26. Velikova, T., Trepova, E., & Rozen, T. (2011). The use of biocides for the protection of library documents: before and now. Science against microbial pathogens: communicating current research and technological advances A. Méndez-Vilas (Ed.), FORMATEX, 152-159.
27. Vonk, J., & Sijpesteijn, A. K. (1971). Methyl benzimidazol‐2‐ylcarbamate, the fungitoxic principle of thiophanate‐methyl. Pesticide Science, 2(4), 160-164. [DOI:10.1002/ps.2780020406]
28. Weaver-Meyers, P. L., Stolt, W. A., & Kowaleski, B. (1998). Controlling mold on library materials with chlorine dioxide: an eight-year case study. The Journal of academic librarianship, 24(6), 455-458. [DOI:10.1016/S0099-1333(98)90006-4]
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